稀土钙钛矿型LaMnO3+λ系列化合物的结构计算与分析     

孙永安  孙立波  王显胜 《世界地质》2005,24(1):102-104

在不同氧分压下合成了LaMnO3 λ、系列化合物，用XRD法进行了结构测定与分析，用化学滴定法测定了Mn^4 含量，由测定结果计算晶胞参数，LaMnO3 λ中系数λ值和La^3 空位率。  相似文献   

晴空日中尺度切变环境场与对流云团发展条件          下载免费PDF全文

雷崇典  师小玲  郑小阳  韩芳琴 《气象》2004,30(1):46-49

重点应用雷达回波资料结合常规气象资料、卫星云图 ,综合分析了 50 0hPa中尺度切变与陕北南部地区对流阵性降水形成、发展条件 ,指出了 50 0hPa不同的中尺度切变与有利的环境合理配置 ,是导致对流云团发展的重要因素 ,不同特征环境风切变配置与对流单体的发展趋势、强度变化、移动和合并息息相关。  相似文献   

基于GIS的单元簇遗传建模及其在区域矿产预测中的应用     

张振飞  高凤亮  马智民  姬金生 《地球科学与环境学报》2001,23(3):15-19

论述一种GIS支持下的基于"单元簇”概念和遗传建模的多源地学信息综合分析方法及在多目标矿产预测中的应用.在以往矿产定量预测中,根据随机抽样思想进行单元划分,对空间信息利用不够充分.用单元的空间组合("单元簇”)代替单元作为定量类比的基本单位,从而能较好实现地质变量值及其所反映的局部地质空间结构的定量类比;将单元作为GIS区图元,利用GIS空间分析功能实现对单元及单元簇的管理和操作;以已知样品判对率最大为适应值计算准则,用遗传算法建立线性判别函数,可快速有效地实现多目标矿产定位预测.以新疆康古尔塔格地区金矿预测实例说明了其应用效果.  相似文献   

A modeling of the structure and favorable H-docking sites and defects for the high-pressure silica polymorph stishovite     

G. V.?GibbsEmail author  D. F.?Cox  N. L.?Ross 《Physics and Chemistry of Minerals》2004,31(4):232-239

Employing first-principles methods, the docking sites for H were determined and H, Al, and vacancy defects were modeled with an infinite periodic array of super unit cells each consisting of 27 contiguous symmetry nonequivalent unit cells of the crystal structure of stishovite. A geometry optimization of the super-cell structure reproduces the observed bulk structure within the experimental error when P1 translational symmetry was assumed and an array of infinite extent was generated. A mapping of the valence electrons for the structure displays mushroom-shaped isosurfaces on the O atom, one on each side of the plane of the OSi₃ triangle in the nonbonded region. An H atom, placed in a cell near the center of the super cell, was found to dock upon geometry optimization at a distance of 1.69 Å from the O atom with the OH vector oriented nearly perpendicular to the plane of the triangle such that the OH vector makes a angle of 91° with respect to [001]. However, an optimization of a super cell with an Al atom replacing Si and an H atom placed nearby in a centrally located cell resulted in an OH distance of 1.02 Å with the OH vector oriented perpendicular to [001] as observed in infrared studies. The geometry-optimized position of the H atom was found to be in close agreement with that (0.44, 0.12, 0.0) determined in an earlier study of the theoretical electron density distribution. The docking of the H atom at this site was found to be 330 kJ mol^–1 more stable than a docking of the atom just off the shared OO edge of the octahedra as determined for rutile. A geometry optimization of a super cell with a missing Si generated a vacant octahedra that is 20% larger than that of the SiO₆ octahedra. The valence electron density distribution displayed by the two-coordinate O atoms that coordinate the vacant octahedral site is very similar to those displayed by the bent SiOSi angles in coesite. The internal distortions induced by the defect were found to diminish rather rapidly with distance, with the structure annealing to that observed in the bulk crystal to within about three coordination spheres.  相似文献   

粉煤灰湿陷变形的三轴试验和计算     

明经平  赵维炳 《岩土力学》2004,25(Z2):32-38

采用双压力室三轴仪对粉煤灰试样进行了单线法湿陷试验,研究了在静水压力作用以及在不同应力状态和应力水平下粉煤灰湿陷变形的规律,得出了粉煤灰湿陷变形的经验计算公式.提出了计算粉煤灰地基湿陷变形的"全应变曲线"增量有限元法.基于本文的试验结果,对一个粉煤灰地基的湿陷变形进行了有限元计算.  相似文献   

Organochlorines and dioxin-like compounds in green-lipped mussels Perna viridis from Hong Kong mariculture zones     

So MK  Zhang X  Giesy JP  Fung CN  Fong HW  Zheng J  Kramer MJ  Yoo H  Lam PK 《Marine pollution bulletin》2005,51(8-12):677-687

Concentrations of persistent organic pollutants including polychlorinated biphenyls (PCBs), organochlorine (OC) pesticides and dioxin-like compounds were measured in green-lipped mussels, Perna viridis, collected from seven mariculture zones in Hong Kong between September and October in 2002 in order to evaluate the status, spatial distribution and potential sources of pollution in these areas. Concentrations ranged from 300 to 4400 ng/g lipid weight for total OCs and 170–1000 ng/g lipid weight for total PCBs (based on 28 congeners). Relatively smaller DDT concentrations in mussels compared with previous studies suggest reduced discharges of DDTs from nearby regions into Hong Kong waters. Detection of a mixture of HCH isomers in the mussels indicated that Hong Kong waters were predominantly contaminated by technical HCHs rather than lindane. Mussel samples from all sampling locations elicited significant dioxin-like activity in the H4IIE-luc bioassay. The greatest magnitude of dioxin-like response (39 pg TEQ/g wet wt.) was detected in mussels from Ma Wan in the western waters of Hong Kong, which is strongly influenced by the Pearl River discharge. Human health risk assessment was undertaken to evaluate potential risks associated with the consumption of the green-lipped mussels. Risk quotient (RQ) for dioxin-like compounds was greater than unity suggesting that adverse health effects may be associated with high mussel consumption.  相似文献   

地壳浅部导电性矿物的一种新的压溶机制：应力原电池过程   总被引：3，自引：0，他引：3  

李和平 《矿物学报》1998,18(1):80-83

以黄铁矿为例,通过导电性矿物的力学-电化学相互作用实验,得出：导电性矿物的电极电位与弹性轴压应力是较好的负线性相关关系。以此为基础,通过电化学理论分析,得出：地壳浅部与溶液接触的导电性矿物颗粒内部存在各种各样的应力原电池,通过应力原电池过程,压溶作用得以实现。导电性矿物应力原电池引起压涛作用的发现,无疑对诸如构造地球化学、地电化学甚至湿法冶金等领域的有关研究具有重要意义。  相似文献   

新矿物(19931～199312)     

黄蕴慧  蔡剑辉  曹亚文 《岩石矿物学杂志》1998,(2)

本文以表格形式列举了１９９３年１月至１９９３年１２月经《国际矿物学协会（ＩＭＡ）新矿物与矿物命名委员会（ＣＮＭＭＮ）》批准并在各国矿物学杂志上发表的４２个新矿物的中文英文名称、化学式及其他数据。数据依次为：矿物的晶系、空间群、晶胞参数、主要粉晶数据（Ｉ、ｈｋｌ）、物理性质（晶形、颜色、条痕、光泽、解理、发光、硬度、密度等）、光学性质（一、二轴晶,正、负光性,折光率,反射率,双反射,２Ｖ,色散,吸收性,多色性等）、产状、共生矿物等。  相似文献   

Study on seismic numerical model on the Chinese mainland and its vicinity     

焦明若  张国民  刘杰  车时 《地震学报(英文版)》1999,12(6):632-639

IntroductionSeismicprocessisextremelycomplicatedjustashasbeenprovedbytheeallhquakepredictionpractice.Thecomplexityofseismicprocessmainlydisplaystheinhomogeneityofseismicspace-timedistribution.Therearealotoffactorscausingthecomplexity,includingthemediumofseismicsource,themechanicalprocessofseismicsource,mutualeffectofgroupseismicactivity,andsoon.Studyontheseismicactivitylawstillremainsinalowlevel,especiallyintheaspectofseismicoccurrenceprocess.Manyscholarstrytostudytheseismicactivebehavioringr…  相似文献   

气候系统可预报性的全局研究   总被引：15，自引：4，他引：11       下载免费PDF全文

范新岗  张红亮  丑纪范 《气象学报》1999,57(2):190-197

胞映射方法是对非线性系统进行全局分析的强有力工具。文中基于一个最大简化的地－气耦合模式,引入胞映射全局分析方法,对气候系统的可预报性进行了全局的研究。气候系统存在最大可预报期限,对于超过逐日预报可预报期限后的预报,用胞映射思想证明了平均值的可预报性,并得到了定量的结果。研究表明,耦合机制具有延长可预报期限的作用,观测精度的提高亦可延长可预报期限  相似文献